A Ce 4+ Aluminum Hydride Complex.

July 11, 2026| Source: Journal of the American Chemical Society

Complexes of reducing hydride ligands by high-oxidation state cerium are unknown due to the fundamental mismatch in their redox chemistry. Herein we report the synthesis, characterization, and reactivity of the first example of a Ce 4+ aluminum hydride complex. Synthetic strategies adapted from the preparation of Ce 4+ alkyl complexes facilitated the isolation of [Ce 4+ (κ 2 -H 3 AlC(TMS) 3 )(NP( t Bu) 3 ) 3 ] ( CeHAl ). The bonding and structure of this complex is characterized by single-

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Nature's antivenom: Combinations of conserved rattlesnake serum metalloproteinase inhibitors block the lethal action of viper venoms.

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Physical/TechAugust 4, 2026

Abrupt transition to irreversible damage in the overdrafted Sacramento Valley aquifer system.

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Physical/TechJuly 28, 2026

Synergistic action of different molecular mechanisms causes striking levels of insecticide resistance in the malaria vector Anopheles gambiae .

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Physical/TechJuly 28, 2026

There is no free benchmark: An institutional view of legal AI benchmarking.

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Physical/TechJuly 28, 2026

A phosphorylation cascade involving ZmSnRK2.10-ZmRIPK2-ZmWRKY38 attenuates drought response by derepressing ZmSUS2 in maize.

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